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PRECIPITATION AND MICROSTRUCTURE OF Cr MODIFIED Al3Ti

W.H. Tian

金属学报(英文版)

The microstructures of Cr modified Al3 Ti containing Al2 Ti and L10-AlTi precipitateshave been investigated in terms of transmission electron microscopy ( TEM). Fine pre-cipitation of Al2 Ti (Ga2Hf type structure) and L 1o-AlTi(Cr) occurs in L l2-Al3 Ti(Cr)by aging around 973K. The aging behavior was investigated by microhardness mea-surements. TEM observations revealed that plate-like Al2 Ti precipitates lie on { 100}planes of the L12-Al3 Ti(Cr) matrix with the c axis of the tetragonal phase perpendic-ular to the thin plate. As contrast with Al2 Ti precipitates, L1o-AlTi(Cr) precipitatesform thin plate and lie on {100} planes of L12-Al3Ti(Cr) matrix at the initial agingtime and for long time aging the habit plane of the thin plate deviated from {100}plane and finally formed a kinked plate. The coherency stresses across the precipi-tate/matrix interface are considered to be the main factor controlling the precipitatemorphology.``

关键词: titanium aluminide , null , null , null , null

MICROSTRUCTURE AND MECHANICAL PROPERTIES OF P/M TiAl ALLOYS AND THE TEMPERATURE EFFECT

Z.M.Sun , H.Hashimoto , S.Sumi , Y.H.Park and T.Abe (Materials Engineering Division , Tohoku National Industrial Research Institute 4-2-1 Nigatake , Miyagino-ku , Sendai 983-8551 , Japan) Z.H. Shan (Research Fellow of Science and Technology Agency of Japan STA)

金属学报(英文版)

Two intermetallic compounds of Ti-50at.% Al and Ti-48at.% Al-2at.% Cr were prepared with a mechanical alloying and pulse discharge sintering process. The as-sintered material showed a microstructure of equiaxed gamma grain with sub-micron size. Heat treatments in vacuum at different temperatures up to 1573K were conducted on the sintered materials. The microstructure of the material coarsened considerably after heat treatment at temperatures higher than 1523K. The mechanical properties of the as-sintered and the heat treated materials were measured at temperatures of up to 973K, with four-point bending tests. Experimental results indicated that the addition of Cr increased the fracture strength of the intermetallic compound at room temperature and at elevated temperatures as well. The bending fracture strength increased with increasing testing temperature up to about 873K and a decreasing followed up. Both fracture strength and fracture strain of the material were found to be improved by heat treatment.

关键词: titanium aluminide , null , null , null , null

INVESTIGATION ON 1/3[111] FRANK LEDGE DISLOCATIONS AT α_2/γINTERFACE IN HOT-DEFORMED Ti-45Al-10Nb ALLOY

J.G WanG , L.C Zhang , G.L. Chenand HQ. Ye(State Key Laboratory for Advanced Metals and Materials , Unborsity of Science and Technology Beijing , Beijing 100083 , China)(Laboratory of Atond Imaging of Solids , Institute of Metal Research , Chinese Academy of Sciences , Shenyang 110015 , China)

金属学报(英文版)

The dislocation ledges at the α2/7 intedece in a hot-dejormed Ti-45Al-10N alloywere analyzed by high-resolution tmnsmission electron microscopy. A new type ofdislocation ledge containing 1/3[111] Frank partial was found. The height of the ledgestDas always three [111]γplanes. The Burpers vectore of these diBlocation ledges weredetermined to be 1/2[110] and 1/2<101] corresponding to the 90 dey. and 30 deg.Shockley partials at noral ledges, i.e. 90 dep. ShockIey Partial dislocation +1/3[111]Frank partial dislocation; and 30 deg. Shockley partial dislocation + 1/3[111] Frankparfial dislocations. The jormation mechanism of this new tare of dislocation ledgewas discussed.

关键词: titanium aluminide , null , null , null

Fractal Dimensions of Hydrogen Induced Brittle Fracture of Titanium Aluminide

Yue ZHANG Yanbin WANG Lijie QIAO Wuyang CHU Chimei HSIAO Dept.of Materials Physics , University of Science and Technology , Beijing , Beijing , 100083 , China

材料科学技术(英)

The relationship between the stress intensity factor K_1~* required for brittle crack initiation and propa- gation and the fractal dimension D_F of the fracture surface was derived,i.e, InK_1~*=(1/2)In2γE'+(1/2)In(d_f/L_0)(1-D_F) The real surface energy can be calculated based on the measured linear relation of the InK_1~* vs D_F, The equation is not only suitable for the overload fracture but also for the delayed fracture,e.g. hydrogen induced cracking (HIC) and stress corrosion cracking (SCC).The experiment results showed that the hydrogen induced delayed cracking occurred in the Ti-24AI-11 Nb alloy during dy- namic charging,and the threshold stress intensity factor was very low,i.e..K_(IH)/K_(IC)= 0.43.The ex- perimental relationship between the stress intensity factor K_1~* and D_F was consistent with the theo- retical equation.

关键词: titanium aluminide , null , null

等温变形对γ-TiAl合金微观组织的影响

黄朝晖

稀有金属材料与工程

通过等温压缩特性及微观组织演变研究,提出了有效的γ-TiAl基合金晶粒细化方法.研究发现,如果γ-TiAl合金锭具有一定的细晶组织便可以在(α2+γ)2相区完成等温变形而不产生裂纹.动态再结晶和静态球化数量的增加是提高γ-TiAl合金变形能力的主要原因.将等温变形的模拟锻件在不同相区进行热处理获得了具有细小尺寸的3种(全片层、近片层和双态)组织.

关键词: TiAl , 等温变形 , 细化 , 组织

Ti-47Al-2Mn-2Nb-0.8TiB_2合金韧脆转变温度及其应变速率敏感性

王瑜 , 林栋梁 , 刘俊亮 , C.C.Law

金属学报

采用拉伸试验,研究厂不同应变速率(10-5-10-1S-1)下温度对台体积分数为0.8%的TiB2、具有近全片层组织的Ti—47Al—2Mn-2Nb金属间化合物的屈服强度和延伸率的影响,得到合金韧脆转变温度随应变速率升高而升高的变化关系,确定这种含TiB2的TiAL合金的韧脆转变激活能为256kJ/mol这一数值低于无TiB2的合金的韧脆转变激活能(324kJ/mol),接近TiAl合金中原子自扩散激活能结合断口分析和理论计算结果,表明这种含TiB2的TiAl合金韧脆转变过程可能受位错攀移机制控制.

关键词: TIAl , intermetullics , BDT , strain rate

热等静压对铸造Ti-47.5Al-2.5V-1.0Cr合金持久性能的影响

朱春雷 , 李海昭 , 骆晨 , 张继

材料热处理学报

将定向层片组织铸造Ti-47.5Al-2.5V-1.0Cr(at%)合金在α+γ两相区分别进行了1270℃,180 MPa下1h,1.5h和2.5h的热等静压处理,然后在800℃和300 MPa条件下进行了持久断裂试验,以研究热等静压处理对该合金持久性能的影响.试验结果表明,在1270℃/180 MPa条件下,热等静压分别持续1h,1.5h和2.5h后,相比未经热等静压处理的铸态试样,其800℃/300 MPa持久寿命均明显降低,降低幅度分别为64.4%,70.2%和82.0%,但其持久塑性均明显提高.结合持久断口的断裂特征分析及微观组织观察认为,热等静压过程中析出的等轴γ晶粒可促进持久加载过程中动态再结晶的发生以及显微空洞的生成,由此导致了持久寿命的降低;此外,相比等轴γ晶粒析出的体积分数,其本身的存在对该合金800℃和300 MPa持久寿命有更直接的影响.

关键词: 热等静压(HIP) , TiAl , 持久性能 , 动态再结晶

应变速率对近全片层组织γ-TiAl合金韧脆转变温度的影响

王瑜 , 林栋梁 , 刘俊亮 , C.C.LAW

金属学报

采用拉伸试验,研究了不同应变速率(10-5-10-1s-1)下温度对具有近全片层组织的γ+α2双相Tial合金的屈服强度和延伸率的影响,得到Tial合金韧脆转变温度随应变速率升高而升高的变化关系,随后确定Tial合金韧脆转变激活能为324kJ/mol.这一激活能数值与Tial合金中原子自扩散激活能相当.结合断口分析和理论计算结果,认为Tial合金韧脆转变过程可能受位错攀移机制控制.

关键词: TiAl , intermetallics , brittle-to-ductile transition , strain rate

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